期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 4, 页码 2867-2881出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.6b03096
关键词
Fast biomass byrolysis; Biomass characterization; Cellulose; hemicellulose; lignin; and extractives; Multistep kinetic mechanism of biomass decomposition; Ash effect on pyrolysis products
资金
- CAPES Foundation, Ministry of Education of Brazil Science without Borders Mobility Program Full PhD Scholarship [10131/13-2]
This paper discusses the research activities done at Politecnico di Milano in the field of the detailed kinetic modeling of pyrolysis and combustion of biomass and bio-oil formation. Different critical steps are involved in this multicomponent, multiphase and multiscale problem. The first complexity relies on biomass characterization with the selection of reference species: cellulose, hemicellulose, lignins, and extractives. Fast pyrolysis involves kinetic mechanisms, first in the solid phase for biomass pyrolysis, then in gas -phase for secondary reactions of released products. These mechanisms involve large number of species and reactions, which make computations expensive. They need to be simplified, while still maintaining their description capability. Lumping procedures are extensively applied to allow the development of the overall model. Multistep pyrolysis mechanisms of reference species are discussed in this Note, with several comparisons with experimental data. A peculiarity of the model is its ability to provide detailed compositions of pyrolysis products and solid residue. Catalytic effect of ash on pyrolysis products is also discussed. A companion paper will discuss the successive or secondary gas phase reactions of pyrolysis products, together with the heterogeneous reactions of residual char. Finally, the modeling of biooil formation requires a comprehensive description of the coupling of kinetic and transport processes, both at the particle and the reactor scale.
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