期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 6, 页码 5175-5182出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b00518
关键词
Photoelectrochemical; Water splitting; MoS2; TiO2; 3D system
资金
- National Natural Science Funds [21676198]
- Program of Introducing Talents of Discipline to Universities [B06006]
A novel three-dimensional (3D) photoanode with exfoliated MoS2 nanosheets on TiO2 nanorod arrays (TiO2 NAs) was successfully fabricated by combining hydrothermal and drop-casting methods. The influences of the different phases (1T and 2H) of the MoS2 nanosheets on the photoelectrochemical (PEC) performances of such a TiO2 NAs/MoS2 3D system have been systematically investigated. Parallel experiments revealed that the TiO2 NAs/1T-MoS2 composite with optimized 1T-MoS2 loading exhibited the highest photoelectric conversion efficiency, which was about 440 and 93% higher than those of the TiO2 NAs and the TiO2 NAs/2H-MoS2 counterpart, respectively. The enhanced catalytic performances of the TiO2 NAs/1T-MoS2 composite can be attributed to the superior conductivity of 1T-MoS2 and the strong interaction between TiO2 NAs and 1T-MoS2. The photogenerated holes can therefore transfer from the TiO2 NAs to the 1T-MoS2, thus leading to enhanced charge separation efficiency.
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