4.6 Article

Ammonia as a Renewable Energy Transportation Media

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 11, 页码 10231-10239

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b02219

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Hydrogen; Energy storage; Renewables; Solar; Wind; Power generation; Automotive; Emissions

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Ammonia synthesized using hydrogen from renewable sources offers a vast potential for the storage as well as transportation of renewable energy from regions with high intensity to regions lean in renewable sources. Ammonia can be used as an energy vector for an emissionless energy cycle in a variety of ways. Ammonia at the point of end use can be converted to hydrogen for fuel cell vehicles or alternatively utilized directly in solid oxide fuel cells, in an internal combustion engine or a gas turbine. One ton of ammonia production requires 9-15 MWh of energy. However, its conversion back to useful form or direct utilization can lead to substantial energy losses. In this paper, we present an overview of the current processes and technologies for ammonia synthesis and its utilization as an energy carrier. We have performed an estimation of the round-trip efficiency of different routes for ammonia utilization at the point of end use along with some sensitivity analysis, and we discuss the outcomes resulting from the best and worst case scenarios.

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