期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 2, 页码 1503-1508出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.6b02127
关键词
Aqueous lithium-ion battery; Polyimide; Activated carbon; Composite anode; LiMn2O4
资金
- National Natural Science Foundation of China [21333002]
- National Key Research and Development Plan [2016YFB0901503]
- Shanghai Science & Technology Committee [13JC1407900]
Polyimide/activated carbon (PI/AC) composites were prepared by in situ polymerization of 1,4,5,8-naphthalenete-tracarboxylic dianhydride (NTCDA) and ethylene diamine (EDA) on activated carbon with various mass ratios varying from 50:50 to 70:30. These composites were examined as anode materials in 5 M LiNO3 solution in the potential window from -0.75 to 0 V vs Ag/AgCl. With an optimal composition PI/AC 50:50 in mass ratio, the composite delivers a specific capacity of 87 mAh g(-1) at a current density of 0.2 A g(-1), and it also shows excellent cycling stability and rate capability. A sealed full cell containing a PI/AC composite anode and LiMn2O4 cathode delivers a specific capacity of 42 mAh g(-1) and energy density of 51Wh kg(1-) (based on the total weight of both active materials) at a current density of 0.2 A g(-1). The full cell exhibits good cycling stability with a specific capacity of 35 mAh g(-1) after 450 cycles, corresponding to a capacity retention of 89%.
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