期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 7, 页码 6036-6045出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b00882
关键词
Polymer-coated urea; Waste frying oil; Polyurethane; Nitrogen release
资金
- National Natural Science Foundation of China [31572201]
- Shandong Agricultural Innovation Team [SDAIT-17-04]
- Natural Science Foundation of Shandong Province [ZR2015CM035]
- projects of commercialization of research findings of Shandong Province [2014 183]
- Great Innovation Projects in Agriculture of Shandong Province [2013 136]
Novel biobased polyurethane (PU) was synthesized by using waste frying oil-based polyol (WFOP) and isocyanate for slow-release fertilizers (SRFs). Epoxy resin (EP) was used to modify PU to synthesize the interpenetrating network (IPN) for improving the properties of the coating film. Nine polymer-coated nitrogen (N) fertilizers were prepared from these composite coating materials. The N release characteristics of the PU-coated urea (PCU) in water and soil were determined. Degradation behavior of coatings in the soil was evaluated. Results showed that 20% EP in the coating increased the cross-linking density by 77.9%, reduced the coating porosity by 28%, and thus slowed the nutrient release from the PCU significantly. Because of its compact structure, the water absorption rate of the EP-modified PCU shell was slower than that of the unmodified ones. All the PCUs, especially the EP-modified ones, showed excellent slow N release behaviors. In addition, the biopolymers derived from waste frying oil also displayed good biodegradability in the soil environment. Findings from this work indicated that the slow release and environmentally friendly PCUs have great potential for applications in horticulture and agriculture.
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