期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 9, 页码 7659-7669出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b00990
关键词
Biobased polymer; Terpene; Alloocimene; Emulsion polymerization; Density functional theory
资金
- CSIR (HRDG), New Delhi [20/12/2015(ii) EU-V]
- Central Research, Bridgestone Corp., Japan
We present the synthesis and characterization of a biobased sustainable polymer from alloocimene, a monoterpene from renewable resources, by redox emulsion polymerization under ambient conditions. Density functional theory was used to determine the ground-state optimized structure of alloocimene. Poly-alloocimene has a molecular weight of 14 200 Da and subzero glass transition temperature of 17 degrees C. The microstructure and properties were determined by FT-IR and NMR (1-D, 2-D) spectroscopies, differential thermal analysis, dynamic mechanical analysis, and thermogravimetry.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据