期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 5, 期 11, 页码 9599-9602出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03260
关键词
CDI; 1,1 '-Carbonyldiimidazole; Mechanochemistry; Ball-milling; Green chemistry; Sustainable chemistry; Solvent-free
资金
- Universite de Montpellier
- Centre National de la Recherche Scientifique (CNRS)
- LabEx CheMlSyst (through ANR programme) [ANR-10-LABX-05-01]
The application of mechanical forces to enable a chemical reaction, also known as mechanochemistry, is actually experiencing an impressive renewal of interest among the chemists community. One major advantage of this approach in organic synthesis lies in the possibility to run essentially solvent-free reactions. In recent years, some research groups have combined these types of solvent-free processes with the use of an eco-friendly reagent: 1,1'-carbonyldiimidazole (CDI). Thus, a wide range of molecules, including carboxylic acids, amines, and alcohols, could react efficiently with CDI under ball-milling conditions. By providing a vast array of products (amides, carboxylic acids, esters, ureas, hydantoins, etc.) in an efficient, fast, user-friendly, and green manner, this approach presents all the prerequisites to soon become a first choice methodology for all organic chemists. The reasons for the past and future successes of this combination are summarized, analyzed, and discussed herein.
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