期刊
ENGINEERING JOURNAL-THAILAND
卷 21, 期 1, 页码 1-16出版社
CHULALONGKORN UNIV, FAC ENGINEERING
DOI: 10.4186/ej.2017.21.1.1
关键词
Metathesis; 2-butene; propylene production; MgO; WO3/SiO2
资金
- Ratchadaphiseksomphot Endowment Fund for International Research Integration: Chula Research Scholar [GCRS_58_02_21_01]
The performances of MgO admixed WO3/SiO2 catalysts were investigated in the cross metathesis of ethylene and 2-butene to propylene at 450 degrees C atmospheric pressure. Compared to the WO3/SiO2 + silica gel, the conversion of 2-butene and the propylene selectivity were much higher on all the WO3/SiO2 + MgO catalysts. An increased propylene yield corresponded to the decrease in 1-butene and cis-2-butene by products. The results in this study also suggest suitable method to prepare highly stable MgO catalysts in order to maximize the propylene yield.
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