期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 16, 页码 2503-2506出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09650f
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Silver(I)-promoted carbene insertion into X-H (X = Si, Sn, and Ge) bonds has been realized by using unstable diazo compounds, which are generated in situ from N-nosylhydrazones as carbene precursors. The reaction tolerates a wide range of functional groups and delivers a number of valuable silicon-containing compounds in very high yields (up to 96%). Moreover, organostannanes and organogermanes were as well effectively obtained in very good yields under optimal conditions.
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