期刊
POLYMERS
卷 9, 期 10, 页码 -出版社
MDPI AG
DOI: 10.3390/polym9100498
关键词
aluminum; heterogeneous catalysis; oxidation of sulfides
资金
- Ministry of Science and Technology, Taiwan [MOST103-2632-M-033-001-MY3, MOST105-2119-M-033-005]
- Chung Yuan Christian University
A series of aluminum-based coordination polymers or metal-organic frameworks (Al-MOFs), i.e., DUT-4, DUT-5, MIL-53, NH2-MIL-53, and MIL-100, have been facile prepared by microwave (MW)-assisted reactions and used as catalysts for selective sulfoxidation reactions. The MW-assisted synthesis drastically reduced the reaction time from few days to hours. The prepared MOFs have smaller and uniform particle sizes and better yield compared to conventional hydrothermal method. Furthermore, the Al-MOFs have been successfully demonstrated as catalysts in oxidation reaction of methyl phenyl sulfide with H2O2 as oxidant, even under mild conditions, with more than 95% conversion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据