期刊
CHEMISTRY LETTERS
卷 46, 期 4, 页码 616-619出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.161192
关键词
Metal sulfide photocatalyst; Hydrogen evolution; Visible light
资金
- JSPS KAKENHI [JP24107001, JP24107004]
- Grants-in-Aid for Scientific Research [24107004] Funding Source: KAKEN
We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d(0), d(5), and d(10) electron configurations. Cu3VS4, Cu3NbS4, and Cu3TaS4 with a sulvanite structure, ZnGaxIn2-xS4 (x = 0-0.6), and MnGaInS4 with layered structures, BaLaCuS3 with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)(0.9)-(CuCl)(0.1) solid solution with a zinc blende structure have arisen as new photocatalysts for H-2 evolution in the presence of sacrificial electron donors under visible light irradiation.
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