期刊
MOLECULAR ASTROPHYSICS
卷 6, 期 -, 页码 22-35出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molap.2017.01.002
关键词
Astrochemistry; ISM: abundances; ISM: molecules
资金
- French CNRS/INSU programme PCMI
- ERC Starting Grant (3DICE) [336474]
Recent laboratory measurements have confirmed that chemical desorption (desorption of products due to exothermic surface reactions) can be an efficient process. The impact of including this process into gasgrain chemical models entirely depends on the formalism used and the associated parameters. Among these parameters, binding energies are probably the most uncertain ones for the moment. We propose a new model to compute binding energy of species to water ice surfaces. We have also compared the model results using either the new chemical desorption model proposed by Minissale et al. (2016) or the one of Garrod et al. (2007). The new binding energies have a strong impact on the formation of complex organic molecules. In addition, the new chemical desorption model from Minissale produces a much smaller desorption of these species and also of methanol. Combining the two effects, the abundances of CH3OH and COMs observed in cold cores cannot be reproduced by astrochemical models anymore. (C) 2017 Elsevier B. V. All rights reserved.
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