期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 20, 页码 4741-4749出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604812
关键词
cluster compounds; molecular junctions; molecular wires; single-molecule electronics; transition metals
资金
- JSPS KAKENHI [26810031]
- Grants-in-Aid for Scientific Research [26810031] Funding Source: KAKEN
Recent developments of single-molecule conductance measurements allow us to understand fundamental conducting properties of molecular wires. While a wide variety of organic molecular wires have been studied so far, inorganic and organometallic molecular wires have received much less attention. However, molecular wires with transition-metal atoms show interesting features and functions distinct from those of organic wires. These properties originate mainly from metal-ligand d-p interactions and metal-metal d-d interactions. Thanks to the rich combination of metal atoms and supporting ligands, frontier orbital energies of the molecular wires can be finely tuned to lead to highly conducting molecular wires. Moreover, the unique electronic structures of metal complexes are susceptible to subtle environmental changes, leading to potential functional molecular devices. This article reviews recent advances in the single-molecule conductance study of inorganic and organometallic molecular wires.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据