期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 14, 页码 3135-3140出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500233
关键词
Synthetic methods; Ketones; Alkenes; Radicals
资金
- Science & Engineering Research Board (SERB), India [SR/FT/CS-81/2011]
- Ministry of Human Resource Development under the Centre of Excellence in FAST [5-7/2014-TS-VII]
A metal-free protocol for the alpha-benzoxylation of ketones has been developed by using terminal aryl alkenes as an aryl-carboxy surrogate. Moderate to good yields were attained for a variety of propiophenones and acetophenones by using tetra-n-butylammonium iodide (TBAI) as the catalyst and tert-butyl hydroperoxide (TBHP) as the oxidant under ambient reaction conditions.
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