期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 28, 页码 4038-4041出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09215b
关键词
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资金
- National Natural Science Foundation of China [21572096, 21302088]
- Shenzhen overseas high level talents innovation plan of technical innovation project [KQCX20150331101823702]
- Shenzhen special funds [JCYJ20150430160022517]
A novel difunctionalization-type (hetero) arylation of unactivated alkenes has been developed via remote 1,4(5)-(hetero) aryl migration triggered by radical alkene azidation, trifluoromethylation, or phosphonylation. The overall process serves as an unusual and reliable approach for straightforward access to diversely substituted ketones with broad functional group compatibility from readily available substrates and reagents.
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