期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 7, 页码 1419-1422出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403538
关键词
Oximes; Halogenation; Oxybromination; Isoxazolines; Palladium; Homogeneous catalysis
资金
- National Natural Science Foundation of China [21302134, 21402134]
- Natural Science Foundation of Jiangsu [BK20130338, BK20140306]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201207]
An oxime-mediated oxychlorination and oxybromination of unactivated olefins relying on palladium catalysis has been developed. A wide range of chlorinated and brominated isoxazolines has been synthesized in moderate to good yields. To demonstrate the value of the method, the brominated isoxazoline has been further converted to other useful synthetic feedstock.
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