期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 7, 页码 1409-1414出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403565
关键词
Luminescence; Helicenes; Triphenylenes; Cycloaddition; Rhodium
资金
- ACT-C from Japan Science and Technology Agency (JST, Japan)
- Grants-in-Aid for Scientific Research [25288103, 14J07502, 26102004, 25620068, 26102009] Funding Source: KAKEN
A 1,1'-bitriphenylene-based sila[7]helicene was synthesized with a high ee value by enantioselective double [2+2+2] cycloaddition of a biaryl-linked tetrayne with a silicon-linked bis(propargylic alcohol) as a key step. This sila[7]helicene exhibited a high tolerance toward racemization, which could be explained by the X-ray crystal structure analysis. With respect to the photophysical properties, this sila[7]helicene exhibited a relatively high fluorescence quantum yield and circularly polarized luminescence activity.
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