期刊
CHEMCATCHEM
卷 9, 期 5, 页码 718-727出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201601144
关键词
amine; asymmetric catalysis; organocatalysts; phosphine; thiourea
资金
- National Basic Research Program of China [973-2015CB856603]
- National Natural Science Foundation of China [20472096, 21372241, 21372250, 21361140350, 20672127, 21102166, 21121062, 21302203, 21421091, 20732008, 21572052]
Since the first example of using a thiourea-amine organocatalyst was reported in 2003, research on thiourea-based amines and phosphines in asymmetric catalysis has shown the excellent performance of chiral thiourea-amine/phosphine organo-catalysts in a variety of highly enantioselective reactions. In this Minireview, the iconic catalysts and transformations are highlighted and discussed.
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