期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 8, 页码 1245-1262出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700042
关键词
C-H activation; C-H bond functionalization; cobalt; (pentamethylcyclopentadienyl)cobalt(III) species; rhodium
资金
- JSPS [JP15H05802]
- Grants-in-Aid for Scientific Research [15H05802] Funding Source: KAKEN
High-valent (pentamethylcyclopentadienyl) cobalt(III) [Cp*Co(III)] catalysts were found as inexpensive alternatives to (pentamethylcyclopentadienyl) rhodium(III) [Cp*Rh(III)] catalysts in the field of C-H bond functionalization, and applied to a variety of transformations. In this review, after the discovery and early examples of Cp*Co(III)-catalyzed C-H bond functionalization are summarized, the unique reactivity and selectivity of Cp*Co(III) and the differences between the cobalt and rhodium catalysis are intensively discussed. Such differences are assumed to be caused by the lower electronegativity, hard nature, and smaller ionic radius of cobalt.
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