期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 15, 页码 13742-13750出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b01378
关键词
silicon carbide nanotubes and nanowires; carbon nanotubes; aerospace applications; in situ mechanical testing; thermal stability
资金
- NASA Jenkins Fellowship
- 3D MURI fund
- Air Force Office of Scientific Research [FA9550-13-1-0084]
- Grants-in-Aid for Scientific Research [16J09248] Funding Source: KAKEN
The most recent and innovative silicon carbide (SiC) fiber ceramic matrix composites, used for lightweight high-heat engine parts in aerospace applications, are woven, layered, and then surrounded by a SiC ceramic matrix composite (CMC). To further improve both the mechanical properties and thermal and oxidative resistance abilities of this material, SiC nanotubes and nanowires (SiCNT/NWs) are grown on the surface of the SiC fiber via carbon nanotube conversion. This conversion utilizes the shape memory synthesis (SMS) method, starting with carbon nanotube (CNT) growth on the SiC fiber surface, to capitalize on the ease of dense surface morphology optimization and the ability to effectively engineer the CNT-SiC fiber interface to create a secure nanotube-fiber attachment. Then, by converting the CNTs to SiCNT/NWs, the relative morphology, advantageous mechanical properties, and secure connection of the initial CNT-SiC fiber architecture are retained, with the addition of high temperature and oxidation resistance. The resultant SiCNT/NW-SiC fiber can be used inside the SiC ceramic matrix composite for a high-heat turbo engine part with longer fatigue life and higher temperature resistance. The differing sides of the woven SiCNT/NWs act as the hook and loop mechanism of Velcro but in much smaller scale.
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