期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 7, 页码 1227-1231出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600962
关键词
symmetric; Dearomatization; Chromium catalysis; Naphthalene; Aldehyde
资金
- Thousand Plan Youth program [NSFC-21421091, XDB20000000]
The asymmetric dearomatization and addition reaction of bromomethylnaphthalenes with aldehydes proceeded smoothly in the presence of carbazole-based bisoxazoline CrCl2 complex to give the corresponding enanioenriched hydroxylated dearomatization products. The excellent chemo-, regio-, diastereo- and enantioselecitivity are remarkable. Furthermore, hydrogenation of the product led to highly elaborated compound containing three contiguous stereogenic centers.
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