期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 22, 页码 3197-3200出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10246h
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资金
- National Natural Science Foundation of China [21572024]
- Natural Science Foundation of Jiangsu Province [BK20151184]
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
The first gold-catalyzed highly regio- and enantioselective carbene insertion into the O-H bonds of 2-pyridones has been realized in the presence of catalytic amounts of chiral dual-gold complexes. The corresponding chiral products were obtained in moderate to good yields, excellent O-selectivity, excellent carbenic selectivity and moderate to excellent enantioselectivities (up to 96% ee).
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