4.7 Article

Boric acid-destabilized lithium borohydride with a 5.6 wt% dehydrogenation capacity at moderate temperatures

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DALTON TRANSACTIONS
卷 46, 期 14, 页码 4499-4503

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00337d

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Boric acid effectively promotes the dehydrogenation of lithium borohydride due to the interactions between protonic and hydridic hydrogen. The simple mixture of LiBH4-(4/3)B(OH)(3) can release 5.6 wt% hydrogen below 180 degrees C with only a trace amount of water, thus constituting a highly attractive single-use hydrogen storage material.

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