期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 33, 页码 4597-4600出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01097d
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Efficient and selective syntheses of 3-hydroxyimino-1-isoindolinones and 3-methylene-1-isoindolinones were achieved via 8-aminoquinoline assisted Cu-promoted coupling of benzamides with nitroalkanes. The reaction was found to go through C-H activation, nitroalkylation followed by intramolecular cyclization. 3-Hydroxyimino-1-isoindolinones were obtained with nitromethane whereas 3-methylene-1-isoindolinones were produced with higher nitroalkanes.
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