期刊
FARADAY DISCUSSIONS
卷 201, 期 -, 页码 63-70出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7fd00017k
关键词
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资金
- National Basic Research Program of China (973 Program) [2014CB931804]
- NSFC [21120102034, 20831002]
A novel ultra-stable metal-organic framework, MCIF-1, [Cu-2(DCI)(2)](MeCN), based on dicyanoimidazole and Cu(I), has been synthesized at room temperature successfully. MCIF-1 shows excellent water stability and can retain crystallinity after soaking in water for about one week. In addition, MCIF-1 also shows exceptional resistance under both acidic and basic conditions within a large pH range from 0 to 13.5. What is more, after modifying the synthesis procedure slightly, we can produce this material in a large scale during a very short time. Mild synthesis conditions, excellent stability and ease of large scale production give MCIF-1 great potential for practical use.
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