期刊
COLLOIDS AND SURFACES B-BIOINTERFACES
卷 153, 期 -, 页码 229-236出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfb.2017.02.025
关键词
Carboxymethyl chitosan; Nanoparticle; Calcium; pH sensitive
资金
- Academy of Finland [283200]
- Academy of Finland (AKA) [283200, 283200] Funding Source: Academy of Finland (AKA)
In environmental applications the applied materials are required to be non-toxic and biodegradable. Carboxymethyl chitosan nanoparticles cross-linked with Ca2+ ions (CMC-Ca) fulfill these requirements, and they are also renewable. These nanoparticles were applied to oil-spill treatment in our previous study and here we focused on enhancing their properties. It was found that while the divalent Ca2+ ions are crucial for the formation of the CMC-Ca, the attractive interaction between -NH3+ and -COO- groups contributed significantly to the formation and stability of the CMC-Ca. The stability decreased as a function of pH due to the deprotonation of the amino groups. Therefore, the nanoparticles were found to be fundamentally pH sensitive in solution, if the pH deviated from the pH (7-9) that was used in the synthesis of the nanoparticles. The pH sensitive CMC-Ca synthesized in pH 7 and 8 were most stable in the studied conditions and could find applications in oil-spill treatment or controlled-release of substances. (C) 2017 The Authors. Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据