期刊
ACS NANO
卷 11, 期 5, 页码 4960-4968出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b01599
关键词
STM; F(4)TCNQ; self-assembly; Kondo effect; epitaxial graphene; Ir(111); DFT
类别
资金
- European Research Council (ERC-StG) [278698]
- Academy of Finland [305635]
- Centres of Excellence Program [284594, 284621]
- European Research Council (ERC) [278698] Funding Source: European Research Council (ERC)
- Academy of Finland (AKA) [305635, 305635] Funding Source: Academy of Finland (AKA)
pi-conjugated organic molecules tend to adsorb in a planar configuration on graphene irrespective of their charge state. In contrast, here we demonstrate charging-induced strong structural relaxation of tetrafluorotetracyanoquinodimethane (F(4)TCNQ) on epitaxial graphene on Ir(111) (G/Ir(111)). The work function modulation over the graphene moire unit cell causes site selective charging of F(4)TCNQ. Upon charging, the molecule anchors to the face-centered cubic sites of the G/Ir(111) moire through one or two cyano groups. The reaction is reversible and can be triggered on a single molecule by moving it between different adsorption sites. We introduce a model taking into account the trade-off between tilt-induced charging and reduced van der Waals interactions, which provides a general framework for understanding charging-induced structural relaxation on weakly interacting substrates. In addition, we argue that the partial sp(3) rehybridization of the underlying graphene and the possible bonding mechanism between the cyano groups and the graphene substrate are also relevant for the complete understanding of the experiments. These results provide insight into molecular charging on graphene, and they are directly relevant for potential device applications where the use of molecules has been suggested for doping and band structure engineering.
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