Metal- and Solvent-Free Approach to Access 3-Se/S-Chromones from the Cyclization of Enaminones in the Presence of Dichalcogenides Catalyzed by KIO3\

Herein, we describe a greener protocol for the one-pot synthesis of 3-Se/S-4H-chromen-4-ones. The desired products were obtained in good to excellent yields using 2hydroxyphenyl enaminones and half equivalents of various odorless diorganyl dichalcogenides (S/ Se) in the presence of glycerol (5 molar equiv) and KIO3 (15 mol %) as the catalyst under solvent-free conditions.