期刊
CHEMPLUSCHEM
卷 82, 期 3, 页码 467-473出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201600611
关键词
copper oxide; heterogeneous catalysis; mesoporous silica
资金
- UGC-UPE Green Technology centre, New Delhi, India
- Ministry of Education, Youth and Sports of the Czech Republic [LO1305, LM2015073]
Hexagonal mesoporous silica (HMS)-supported copper oxides (CuO/HMS) have been prepared by a sol-gel method and characterized by X-ray diffraction, FTIR spectroscopy, transmission electron microscopy, N-2 sorption, inductively coupled plasma (ICP), X-ray photoelectron spectroscopy (XPS), H-2 temperatureprogramed reduction (TPR), NH3 temperature-programed desorption (TPD), and high-resolution (HR)-TEM techniques. An analysis of these results revealed a mesoporous material system with a high surface area (974 m(2)g(-1)) and uniform pore-size distribution. The catalytic efficacy of CuO on the HMS support with varying Cu loadings (1, 3, 5, 10, and 15 wt%) was investigated for the transformation of aldehydes to primary amides; 3wt% CuO/HMS exhibited good catalytic performance with good to excellent yields of amides (60-92%) in benign aqueous medium. The intrinsically heterogeneous catalyst could be recovered after the reaction and reused without any noticeable loss in activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据