4.7 Article

Evaporation rate-based selection of supramolecular chirality

期刊

CHEMICAL COMMUNICATIONS
卷 53, 期 21, 页码 3066-3069

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09842h

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资金

  1. special fund of the Institute of Industrial Science, The University of Tokyo
  2. Ogasawara Foundations for the Promotion of Science Technology
  3. Ministry of Education, Culture, Sports, Science, and Technology of Japan [16H04128]
  4. Grants-in-Aid for Scientific Research [16H04128] Funding Source: KAKEN

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We demonstrate the evaporation rate-based selection of supra-molecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.

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