期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 21, 页码 3078-3081出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00632b
关键词
-
资金
- NSFC [21622202, 21290180, 21502125]
Enantioselective synthesis of SiMe3/SiPh2Me-substituted crotyl geminal bis(silane) has been developed. This compound is a useful reagent for Ph3C+B(C6F5)(4) (-) -catalyzed asymmetric Sakurai allylation and one-pot Sakurai allylation/Prins cyclization processes. Chemo-selective desilylation of SiPh2Me leads to efficient chirality transfer.
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