期刊
DIAMOND AND RELATED MATERIALS
卷 73, 期 -, 页码 121-131出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2016.08.010
关键词
Field emission; Few-layer graphite; Microcrystalline diamond; Ultra-nano-crystalline diamond; Plasma-enhanced chemical vapor deposition
类别
资金
- Ministry of Science and Technology, Taiwan [102-2221-E-007-025-MY3]
The purpose of this study is to fabricate a composite film of bristling few-layer graphite on an octagonal shaped diamond-tip array and to measure the field emission characteristics. The composite film of bristling few-layer graphite on an octagonal shaped diamond-tip array is firstly proposed to improve the field emission effect and lifetime because of the high pitch height ratio of bristling few-layer graphite and the high stability of diamond. The microcrystalline and ultra-nano-crystalline diamond-tip arrays with the shape of an octagonal cone are formed by microwave plasma-enhanced chemical vapor deposition on a silicon substrate. Changing the flow rates of gasses when the bristling few-layer graphite are deposited on the diamond film leads to different results and find out the ideal fabrication parameters for improving field emission. The diamond-tip arrays and bristling few-layer graphite morphology are then examined by Raman spectroscopy and scanning electron microscopy. The field emission effect with different few-layer graphite/diamond composite arrays is also examined. In this study, the composite film of bristling few-layer graphite structures on diamond-tip arrays grown by N-2/H-2/CH4 = 40/80/20 showed excellent field emission stability and high field emission characteristics with low turn-on field of 2.60 V/mu m and the field enhancement factor of 1921. (C) 2016 Published by Elsevier B.V.
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