期刊
DALTON TRANSACTIONS
卷 46, 期 15, 页码 4898-4901出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00631d
关键词
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资金
- Frontier Sciences Research Program of the Chinese Academy of Sciences [QYZDJ-SSW-SLH033]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- National Natural Science Foundation of China [21373221, 21521061, 51672271, 21671190, 21403236]
- Natural Science Foundation of Fujian Province [2006L2005]
The first visible-light-responsive photochromic polyoxometalate-templated lanthanide-organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative, which displays an unusual four-fold interpenetration of an srs topological network, featuring a variety of anion-pi interactions between polyoxoanions and pi-acidic NDI moieties, and undergoes a rapid reversible photochromic transformation upon blue light irradiation.
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