期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 18, 页码 5091-5095出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700559
关键词
alkenylation; C-H activation; cross-coupling; palladium
资金
- National Natural Science Foundation of China [21372210, 21672198]
- State Key Program of National Natural Science Foundation of China [21432009]
A hydroxy group chelation-assisted stereospecific oxidative cross-coupling reaction between alkenes was developed under mild reaction conditions. In the presence of palladium catalyst, the alkenes tethered with hydroxy functionality can couple efficiently with electron-deficient alkenes to form the corresponding multi-substituted olefin products. The hydroxy group on the substrate could play dual roles in reaction, acting as the directing group for alkenyl C-H bond activation and controlling the stereoselectivity of the products.
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