期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 26, 页码 3653-3656出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09675a
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- ERC
Using a specially designed magnesium metallating manifold, combining kinetically activated TMP amide base with a sterically amplified beta-diketiminate ligand, this study has established a new regioselective strategy for magnesiation of challenging N-heterocyclic molecules. The broad scope of the approach is illustrated through reactions of pyrazine, triazoles and substituted pyridines by isolation and structural elucidation of their magnesiated intermediates.
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