期刊
CHEMCATCHEM
卷 9, 期 7, 页码 1149-1156出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201601624
关键词
cascade; catalysis; C-H activation; palladium; remote; spirocycles
资金
- MINECO [CTQ2015-69568-P]
- Fundacion Seneca [19890/GERM/15]
The transition-metal-directed C-H activation processes have traditionally required the installation of suitable coordinating groups to place the metal in close proximity to an specific neighboring or remote C(sp(2))-H or C(sp(3))-H moiety of the molecular structure. Alternatively, substitution of C-H bonds at positions previously thought inaccessible are now performed through domino processes via insitu generated sigma-alkyl-Pd-II species. This Concept article highlights on recent developments which utilize these sigma-alky-Pd-II-species for remote C-H functionalization to reinvigorate new C-C bond formation in cascade fashion via use of catalytic palladium metal.
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