Crystal structure of η′-Fe3Al8; low-temperature phase of η-Fe2Al5 accompanied by an ordered arrangement of Al atoms of full occupancy in the c-axis chain sites

The low-temperature phase of eta-Fe2Al5 has been identified experimentally for the first time and the crystal structure of the low-temperature phase (designated as eta') has been refined by scanning transmission electron microscopy, combined with first-principles calculations. The low-temperature eta' phase has a tripled superlattice structure based on the orthorhombic eta-Fe2Al5 (space group Cmcm), in which Al atoms occupy two ninths of the partially occupied Al sites (Al2 and Al3) in a chain along the c-axis of the orthorhombic parent lattice in an ordered manner, giving rise to the monoclinic space group C2/c, the stoichiometric composition Fe3Al8 (Al-27.3 at%Fe), and the Pearson symbol mC44. The partially occupied Al sites along the c-axis of the orthorhombic parent lattice are converted to the Al site (Al3 site) of full occupancy in the monoclinic superlattice of the eta'-Fe3Al8. The eta-eta'phase transformation temperature decreases from between 350 and 400 degrees C at the composition of Al-26.7 at.%Fe to between 300 and 350 degrees C at compositions in the range of Al-27.3 to 28.6 at.%Fe, indicating that the eta' phase exists primarily at the Fe-lean side of the solid-solubility region of the eta-Fe2Al5 phase. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.