期刊
CHEMISTRY LETTERS
卷 46, 期 5, 页码 655-658出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170037
关键词
C-H borylation; Anthracene; Cross-coupling
Iridium-catalyzed direct tetraborylation of anthracene to give 1,3,5,7-tetrakis(Bpin)anthracene 5 was achieved by using a combination of [Ir(OMe)(COD)](2) and tmphen as the catalyst. Compound 5 was applied to the synthesis of 1,3,5,7-tetraaryl-anthracenes 7 as a new molecular entity. The latter showed long fluorescence lifetime in the solid state.
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