期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 32, 页码 4445-4448出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00754j
关键词
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资金
- National Science Foundation's Environmental Chemical Sciences program [CHE-1610728]
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1610728] Funding Source: National Science Foundation
This study introduces a new and previously unconsidered fast abiotic formation of Mn(IV) oxides. We report photochemically assisted fast abiotic oxidation of Mn2+ (aq) to Mn(IV) (s) by superoxide radicals generated from nitrate photolysis. This photochemical pathway generates randomly stacked layered birnessite (delta-MnO2) nanosheets.
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