期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 24, 页码 5799-5803出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201700172
关键词
ethanol electrooxidation; glycerol electrooxidation; nanoparticles; palladium; tetrahedral; trigonal bipyramidal
资金
- National Natural Science Foundation of China [91430217, 21427811]
- MOST China [2016YFA0203200]
Well-defined palladium trigonal bipyramidal/tetrahedral nanocrystals were synthesized by an aqueous-phase hydrothermal method. The final products were a mixture of trigonal bipyramidal and tetrahedral nanocrystals. Statistics indicated that there were more trigonal bipyramids than tetrahedra in the products. Ethylenediamine tetraacetic acid disodium salt (EDTA-2Na) was proven to be essential in controlling the final shapes of palladium nanocrystals. Some control experiments were also conducted to investigate the shape evolution and formation mechanisms. The synthesized palladium nanocrystals showed enhanced catalytic properties for ethanol and glycerol electrooxidation in alkaline medium. This work provides a new method in preparing Pd nanomaterials with well-defined shapes.
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