期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 10, 页码 1725-1734出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700011
关键词
3-aminooxindoles; asymmetric decarboxylation reaction; isatin imines; -keto acids; organocatalysis
资金
- UGC
- UGC-BSR
- CSIR India [02(0239)/15/EMR-II]
- Department of Science and Technology (DST), India under FIST programme
- UGC, India
An efficient chiral squaramide-catalyzed enantioselective decarboxylative addition reaction of -keto acids to isatin imines has been developed. The reaction proceeds smoothly using 20mol% of organocatalyst to afford the chiral 3-aminooxindoles in high yield and excellent enantioselectivities.
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