期刊
CHEMICAL ENGINEERING SCIENCE
卷 163, 期 -, 页码 114-122出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2017.01.036
关键词
Sorption-enhanced steam methane; reforming; Core-shell structure; Bifunctional material; H-2 production; Stability
资金
- National Natural Science Foundation of China [21276076]
- Program for New Century Excellent Talents in University [NCET-13-0801]
- Fundamental Research Funds for the Central Universities [222201313011]
- 111 project [B08021]
Sorption-enhanced steam methane reforming (SESMR) is a promising technology for H-2 production, which can be further enhanced at the particle scale by using core (sorbent)-shell (catalyst) structured bifunctional materials. However, it is challenging but desirable to develop such materials with high activity and stability. In this work, three core-shell structured CaO-Ca9Al6O18@Ca5Al6O14/Ni bifunctional materials with varying CaO content and core/shell mass ratio were prepared by a two-step sol-gel method, and two others (Ni/CaO and CaO@Ca5Al6O14/Ni) served as references. The structural properties and catalytic performance of the materials were investigated. The results showed that all core-shell materials during cyclic SESMR operation had much better performance than Ni/CaO with regards to activity, stability and CaO utilization, and CaO-Ca9Al6O18@Ca5Al6O14/Ni was generally superior to CaO@Ca5Al6O14/Ni except when the former had a much higher CaO content than the latter. The excellent performance of CaO-Ca9Al6O18@Ca5Al6O14/Ni was mainly due to the stabilization effect of Ca9Al6O18 and the support effect of Ca5Al6O14. The best material was a CaO-Ca9Al6O18@Ca5Al6O14/Ni with a CaO content of 13 wt% and a core/shell mass ratio of 0.2, showing high activity and stability over 60 SESMR cycles while maintaining nearly complete utilization of CaO. (C) 2017 Elsevier Ltd. All rights reserved.
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