期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 29, 页码 7024-7030出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201606059
关键词
-
资金
- National Science Centre [SONATA 2013/11/D/ST5/O2956, OPUS 2012/07/B/ST5/02016]
- Ministry of Science and Higher Education [0141/DIA/2015/44]
- Wroclaw Centre for Networking and Supercomputing [432]
Vitamin B-12 is a cofactor for many enzymes, but it also functions as a catalyst in C-C bond-forming reactions. Herein, the impact of corrin structural modifications on their catalytic efficacy was examined. Derivatives with various substituents at c-, d-, and meso-positions were synthesised by using traditional and new microwave methodologies, and then tested in the model reaction of 1,1-diphenylethylene with ethyl diazoacetate. To complement the experimental data, cyclic voltammetry and DFT calculations were performed. Mainly alterations at the c- or d-positions influence both the reaction yield and selectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据