期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 210, 期 -, 页码 495-503出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2017.04.023
关键词
Sustainable chemistry; Ecocatalysis; Bio-sourced catalyst; Reduction; Phytoextraction
资金
- Agence Nationale de la Recherche (ANR) [11ECOT01101]
- Agence de l'Environnement et de la Maitrise de l'Energie (ADEME)
- Centre National de la Recherche Scientifique (CNRS)
- Societe Le Nickel (SLN)
- South Province of New Caledonia
The transfer hydrogenation of carbonyl compounds into alcohols with isopropanol has emerged as a green alternative to the use of hazardous reducing agents. Ni(O) nanoparticles have been described as an efficient catalyst for this reaction, while their classical preparation is still associated with a number of safety and environmental concerns. Here, we report a sustainable, ecological and straightforward preparation of a biosourced Ni(O) based material, by thermal decomposition of Ni(II) formate made from a Ni hyperaccumulating plant. The resulting catalyst, EcoNi(O), shows high catalytic activity and selectivity for the transfer hydrogenation of carbonyl compounds, including challenging aldehydes. The process seeks to be an incentive for the economic development of phytoextraction. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据