期刊
ACS MACRO LETTERS
卷 6, 期 3, 页码 224-228出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.7b00056
关键词
-
资金
- National Natural Science Foundation of China [21674059]
The high incompatibility of block copolymers consisting of a neutral stabilizer block and a polyelectrolyte core-forming block is exploited to drive phase segregation during polymerization-induced self-assembly (PISA). A modular approach to systematically tune the solubility of ionic monomers/polymers is developed to efficiently identify monomers suitable for aqueous dispersion polymerizations. The strong phase segregation ability of the neutral-polyelectrolyte block copolymers favors the formation of worms over a relatively broad composition range and even at very low solids. These findings suggest that the degree of incompatibility between the stabilizer block and the core-forming block should be considered as one of the key parameters when studying morphological transitions in PISA.
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