期刊
ACS MACRO LETTERS
卷 6, 期 4, 页码 326-330出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.7b00037
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资金
- National Key Basic Research Program of China [2015CB351903]
- National Natural Science Funds for Distinguished Young Scholar [21625402]
- National Natural Science Foundation of China [21474084, 21474090]
- Chinese central government's Recruitment Program of Global Experts
Thermoset shape memory polymer (SMP) with dynamic covalent bonds in the network is a new class of SMPs for which the permanent shape can be reconfigured via topological rearrangement (plasticity). Catalyzed transcarbamoylation has recently been established as an effective exchange reaction for plasticity in cross-linked polyurethane networks. However, ensuring the plasticity severely constrains the network design which adversely affects the ability to tune other classical shape memory properties for practical applications. Facing this new challenge, we design an amorphous polyurethane system for which the cross-linking density can be adjusted in a wide range. We discovered that the use of an aromatic diisocyanate in the synthesis of the polyurethanes facilitates achieving plasticity without requiring any catalyst. The overall network design leads to tunable recovery stress and shape memory transition temperatures without sacrificing the plasticity. The versatility of our polyurethane SMP is further reflected in its anticipate that our tunable polyurethanes will benefit a variety of potential SMP device triple-shape memory performance. We applications.
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