期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 20, 页码 16987-16995出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b01109
关键词
Cobalt phosphide; nanowire arrays; supercapacitor; negative electrode material; flexible
资金
- Louisiana Board of Regents [LEQSF(2011-13)-RD-B-08]
- JSPS KAKENHI [JP26420693]
- National Science Foundation [DMR-1262904]
- Grants-in-Aid for Scientific Research [26420693] Funding Source: KAKEN
Despite the great progress that has been accomplished in supercapacitors, the imbalance of the development of positive and negative electrode materials still remains a critical issue to achieve high energy density; therefore, exploring high-performance negative electrode materials is highly desirable. In this article, three-dimensional cobalt phosphide (CoP) nanowire arrays were synthesized on a carbon cloth and were utilized as a binder-free supercapacitor negative electrode. The as-synthesized CoP nanowire arrays presented a high capacitance of 571.3 mF/cm(2) at a current density of 1 mA/cm(2). By using CoP nanowire arrays as the negative electrode and MnO2 nanowire arrays as the positive electrode, a flexible solid-state asymmetric supercapacitor has been fabricated and has exhibited excellent electrochemical performance, such as a high energy density of 0.69 mWh/cm(3) and a high power density of 114.2 mW/cm(3). In addition, the solid-state asymmetric supercapacitor shows high cycle stability with 82% capacitance retention after 5000 charge/discharge cycles. This work demonstrates that CoP is a promising negative electrode material for high-performance supercapacitor applications.
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