期刊
DALTON TRANSACTIONS
卷 46, 期 17, 页码 5493-5497出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt04465d
关键词
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资金
- U.S. National Science Foundation [CHE-1554787]
- Purdue University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1554787] Funding Source: National Science Foundation
A family of low-valent Ni-2, Co-2, and Fe-2 naphthyridine-diimine (NDI) complexes is presented. Ligand-based pi* orbitals are sufficiently low-lying to fall within the metal 3d manifold, resulting in electronic structures that are highly delocalized across the conjugated [NDI]M-2 system. This feature confers stability to metalmetal interactions during two-electron redox reactions, as demonstrated in a prototypical oxidative addition of allyl chloride.
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