期刊
ELECTROCHIMICA ACTA
卷 237, 期 -, 页码 248-258出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.03.158
关键词
Lithium ion battery; Elevated temperature; Degradation mechanism; Active lithium; Electrolyte decomposition
资金
- National High Technology Research and Development Program (863 Program) of China [2012AA110203]
- National Natural Science Foundation of China [51634003]
In this work, the commercial Li batteries are cycled under C/3 rate at room temperature (25 degrees C), 35 degrees C, 45 degrees C and 55 degrees C respectively, and the cycle lifetime is 615 days, 404 days, 159 days and 86 days respectively, which indicates that the capacity fade is strongly dependent upon the ambient temperature. The degradation mechanism of battery capacity is analyzed by the electrochemical and physical characterization. At room temperature, the major reason for the capacity fade of full cells is the irreversible loss of active lithium due to the generation and reformation of SEI film. However, when the ambient temperature exceeds 35 degrees C, the electrolyte decomposition is greatly enhanced by the elevated temperature which could significantly accelerate and dominate the consumption rate of active lithium. Meanwhile, the elevated temperature has an adverse influence on the performance of LiFePO4 material. In addition, the proportions of effects caused by structure degradation and the surface layer for single electrodes are calculated respectively. Through a series of testing experiments, it is concluded that the degradation mechanism is changed when the test temperature is equal or higher than 45 degrees C, and the elevated temperature is not a suitable stress factor to accelerate the aging of full cells. (C) 2017 Published by Elsevier Ltd.
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