期刊
DALTON TRANSACTIONS
卷 46, 期 18, 页码 5911-5917出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00477j
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资金
- NISER Bhubaneswar
- Council of Scientific and Industrial Research (CSIR), Govt. of India [01(2808)/14/EMR-II]
The crystallographic signatures and characterization of two novel mixed metal hybrid open-frameworks [Na2Mn2(C2O4)(SO3)(2)(H2O)(2)] 1 and [NaEu(C2O4)(SO3)(H2O)(3)] 2 are reported for the first time; they are synthesized under hydrothermal conditions to generate 3D assemblies and honeycomb-like structures. They were further characterized by complementary techniques like PXRD, TGA and DSC. The magnetic properties of 1 show antiferromagnetic interactions between the metal centers and compound 2 shows good photoluminescence properties.
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